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Photoluminescence and band offsets of AlInAs/InP

Identifieur interne : 01C393 ( Main/Repository ); précédent : 01C392; suivant : 01C394

Photoluminescence and band offsets of AlInAs/InP

Auteurs : RBID : Pascal:96-0047626

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English descriptors

Abstract

We report the temperature dependence of Al0.46In0.54As photoluminescence (PL) transition energies and Al0.46In0.54As/InP interface staggered line-up luminescence (SLL) energy. The S shape appearing from 4 to 90 K on the energy versus temperature curves of these PL energies is due to extrinsic recombinations. In particular, the S shape of the SLL energy curve versus temperature is probably due to acceptor impurities localized in AllnAs, at the interface (on-edge impurities). The binding energy of on-edge impurities is lower than its value in the bulk material. This explains why the S shape is less pronounced on the SLL than on the AllnAs PL curve. The band offsets were determined by solving the Schrödinger-Poisson equation system with a self-consistent calculation program. At 4.5 K, the conduction and valence band offsets of the Al0.46In0.54As/InP interface were respectively 0.384 eV and 0.295 eV. This is in agreement with the already reported value of 410 meV for the conduction band offset of the lattice-matched Al0.48In0.52As/InP heterostructure. The temperature dependence of the conduction and valence band offsets is shown to be important : respectively 35 meV and 23 meV between 4.5 and 300 K. The Van Vechten-Malloy model (following a thermodynamic approach) for the temperature dependence of the band offsets is compared with our results. The comparison shows only a qualitative agreement.

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Pascal:96-0047626

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<div type="abstract" xml:lang="en">We report the temperature dependence of Al
<sub>0.46</sub>
In
<sub>0.54</sub>
As photoluminescence (PL) transition energies and Al
<sub>0.46</sub>
In
<sub>0.54</sub>
As/InP interface staggered line-up luminescence (SLL) energy. The S shape appearing from 4 to 90 K on the energy versus temperature curves of these PL energies is due to extrinsic recombinations. In particular, the S shape of the SLL energy curve versus temperature is probably due to acceptor impurities localized in AllnAs, at the interface (on-edge impurities). The binding energy of on-edge impurities is lower than its value in the bulk material. This explains why the S shape is less pronounced on the SLL than on the AllnAs PL curve. The band offsets were determined by solving the Schrödinger-Poisson equation system with a self-consistent calculation program. At 4.5 K, the conduction and valence band offsets of the Al
<sub>0.46</sub>
In
<sub>0.54</sub>
As/InP interface were respectively 0.384 eV and 0.295 eV. This is in agreement with the already reported value of 410 meV for the conduction band offset of the lattice-matched Al
<sub>0.48</sub>
In
<sub>0.52</sub>
As/InP heterostructure. The temperature dependence of the conduction and valence band offsets is shown to be important : respectively 35 meV and 23 meV between 4.5 and 300 K. The Van Vechten-Malloy model (following a thermodynamic approach) for the temperature dependence of the band offsets is compared with our results. The comparison shows only a qualitative agreement.</div>
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<sub>0.46</sub>
In
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In
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As/InP interface staggered line-up luminescence (SLL) energy. The S shape appearing from 4 to 90 K on the energy versus temperature curves of these PL energies is due to extrinsic recombinations. In particular, the S shape of the SLL energy curve versus temperature is probably due to acceptor impurities localized in AllnAs, at the interface (on-edge impurities). The binding energy of on-edge impurities is lower than its value in the bulk material. This explains why the S shape is less pronounced on the SLL than on the AllnAs PL curve. The band offsets were determined by solving the Schrödinger-Poisson equation system with a self-consistent calculation program. At 4.5 K, the conduction and valence band offsets of the Al
<sub>0.46</sub>
In
<sub>0.54</sub>
As/InP interface were respectively 0.384 eV and 0.295 eV. This is in agreement with the already reported value of 410 meV for the conduction band offset of the lattice-matched Al
<sub>0.48</sub>
In
<sub>0.52</sub>
As/InP heterostructure. The temperature dependence of the conduction and valence band offsets is shown to be important : respectively 35 meV and 23 meV between 4.5 and 300 K. The Van Vechten-Malloy model (following a thermodynamic approach) for the temperature dependence of the band offsets is compared with our results. The comparison shows only a qualitative agreement.</s0>
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